Abstract
The vibronic pattern of the visible absorption spectra of Rhodamine 3B is studied in terms of Gaussian contributions. The vibronic components 0←0 and 1←0 correlate linearly with Onsager's reaction field function of induced polarisation, f(n2). The respective solvent dependences follow opposite trends. The spectral shape does not sense significant contributions from orientation polarisation or Boltzmann weighted population redistribution.
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