Abstract
The kinetics of aquation of α- and β- cis[Co(edda)Cl2]−, α- cis[Co(edda)(H2O)Cl] and α- cis[Co(trien)Cl2]+ were investigated in aqueous mixtures of t-BuOH, MeOH, DMSO, ethylene carbonate and urea. The transfer Gibbs energy values for the reactants, evaluated from the solubility of the complexes, confirm the decisive role of the reactant solvation on the aquation rate.
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