Solvent Effect on the Synthesis of Oleylamine Modified Au Nanoparticles and Their Self-Assembled Film for SERS Substrate

Abstract

The preparation and self-assembling of monodisperse gold nanoparticles (Au NPs) is of great significance for its SERS application. According to the oleylamine-reduced method, oleylamine (OAm) serves as the reducing agent and stabilizing agent, and the effects of different reaction parameters such as solvent and temperature on the size and dispersity of Au NPs have been evaluated. The Au NPs synthesized with toluene as the solvent have the best dispersity and narrowest particle size distribution with adjustable sizes. The particle size gradually increases with the increase in reaction temperature. The highly ordered self-assembly film of Au NPs was employed as surface-enhanced Raman scattering (SERS) substrate for the probing molecule of rhodamine 6G. The Au substrate exhibits excellent spatial uniformity and SERS reproducibility, which indicates its practicability as a substrate. This study provides a simple synthesis strategy of highly ordered monodispersed Au NPs, which can serve as a SERS substrate with excellent spatial uniformity and SERS re-producibility.