Abstract
The standard potentials of the silver-silver bromide electrode have been determined over a broad range of methanol concentrations from e.m.f. measurements of the cell Pt, H 2 (g, 1 atm); HBr(m), X% methanol, Y% water; AgBr, Ag at eight temperatures ranging from 20 to 55°C. The standard e.m.f. has been expressed as a function of temperature. Thermodynamic functions of cell process, the primary medium effect of various media on hydrobromic acid, and thermodynamics of transfer of HBr from water to methanolic media have been computed and discussed in the light of ion-solvent interactions as well as the structural changes of the solvents.
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