Abstract
Abstract The thermodynamic and spectrophotometric properties of the charge transfer complexes of tetracyanoethylene with mesitylene and benzene are studied in cyclohexane, carbon tetrachloride, chloroform, dichloromethane and in addition the properties of the former complex are studied in benzene. The results show that these properties depend on the solvent. This important role of the solvent in changing both thennodynamic as well as spectrophotometric properties of these complexes is assumed to be due to the solvent interaction with tetracyanoethylene. An attempt is made to calculate the thermodynamic properties of the solvent-tetracyanoethylene interaction.
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