Solvent-dependent strategy to construct mesoporous Zr-based metal-organic frameworks for high-efficient adsorption of tetracycline

Abstract

The accumulated antibiotics in the aquatic environment pose great threat to human and ecological health, boosting the development of porous materials for antibiotic removal. Mesoporous metal-organic frameworks (MOFs) have shown great promise in adsorption, which, however, usually need supramolecular design or cooperative template strategy for synthesis. Here we report the successful construction of mesoporous zirconium based metal-organic frameworks (Zr-MOFs) via a simple solvent-dependent strategy. Regulation of the ratio of water to N, N-dimethylacetamide during synthesis determined the porous structure of the synthesized MOFs. Systematic characterizations including SEM, FTIR, XRD and nitrogen sorption isotherm were carried out for structure analysis of the MOFs. With water fraction of 20% (v/v), the obtained Zr-MOF exhibited the highest adsorption capacity (Qmax of 337.0 mg⋅g−1) towards tetracycline (TC). The adsorption kinetics fitted the pseudo-second-order kinetics, and the adsorption isotherms fitted the Freundlich model well. Adsorption mechanism investigation revealed that the abundant Zr–OH groups stemming from coordination defects mainly accounted for TC adsorption. The hydrogen bonding interaction between TC and Zr-MOF and the generated mesopores contributed to the satisfactory adsorption capacity. This work is anticipated to provide insights on facile synthesis of mesoporous MOFs and application in environmental remediation.