Abstract
The deuterium quadrupole coupling constant in deuterochloroform was determined in an inert solvent (C6H12) and in polar solvents (neat liquid, C6H6, and THF), by combining NMR relaxation data with Raman line shape analysis of the ν1 band (2253 cm−1) of deuterochloroform. The QD value in a 20 mol % solution of CDCl3 in C6H12 was found to be (186±4 kHz), significantly higher than any previously reported value obtained in liquid crystals. A substantial lowering of the quadrupole coupling constant was observed in polar solvents.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
