Abstract
Solvatochromic behaviour is described for the water-soluble molybdenum(0)-carbonyl-diimine complexes [Mo(CO) 4(LL)] n− , where LL=fz (ferrozine;3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine-p,p′-disulphonate) and n = 2 or LL = sb (Schiff base from 2-acetyl pyridine plus β-alanine) and n = 0, in water and in a range of non-aqueous solvents, and in water-isopropanol solvent mixtures. The possibility of using solvatochromic compounds of this type to probe selective solvation in solvent mixtures is assessed, with particular reference to water-isopropanol and acetone-chloroform mixtures, and to microemulsions.
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