Abstract

The influence of the composition of the water-N,N-dimethylformamide mixed solvent on the position of the B absorption band in UV spectra of 2-methoxyphenol, its para-substituted derivatives, and corresponding phenolate anions simulating base units of natural lignin is investigated. The data obtained are interpreted in terms of the model of preferential solvation. The preferential solvation parameters and compositions of the solvation shells are calculated.

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