Abstract
Solvation of lithium ions in the organic electrolyte solutions for primary lithium batteries was investigated by electrospray ionization-mass spectroscopy (ESI-MS). In LiBF 4/γ-butyrolactone (GBL), lithium ions were solvated to GBL molecules in the form [Li(GBL) 2] + or [Li(GBL) 3] +, and in LiClO 4/ dimethoxyethane (DME)–propylene carbonate (PC), lithium ions were solvated mainly to DME and PC in the form [Li(DME)(PC)] +.
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