Abstract
The bulk nanostructure of several inorganic salt solutions in protic ionic liquids is elucidated using neutron diffraction and empirical potential structure refinement modeling. The protic ionic liquids studied are ethylammonium nitrate (EAN) and ethanolammonium nitrate (EtAN), which are mixed with either LiNO3, Mg(NO3)2, Ca(NO3)2, or Al(NO3)3 at 1:10 or 1:30 solute:solvent mol:mol ratios. The models show inorganic metal ions are solvated within the polar domains of the nanostructure and can induce significant differences in bulk solvent nanostructure from that of the pure ionic liquids. For EtAN, the uncharged groups aggregate and form an apolar domain in spite of the cation’s reduced amphiphilicity because the trans rotamer is favored when an inorganic salt is added.
Accepted Version (
Free)
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
