Abstract
Abstract The external ionization potentials for alkylbenzenes in acetonitrile and nitrobenzene have been measured by photoelectron emission spectroscopy to determine electronic polarization energies and reorganization energies. The polarization energy is used to discuss the solvation structure of alkylbenzene. The solvation behavior of alkylbenzene is found to be different from that of butylamine, previously reported. We have obtained the evidence of the approach of solvent molecules to the plane of benzene ring.
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