Abstract

The existence of heteronuclear complexes formed between citric acid, copper(II) and nickel(II) or magnesium(II) is demonstrated. The stoichiometry and stability of the complexes are reported. A volumetric example demonstrates the unexpectedly high stability of the CuNicitrate complex in comparison with the binary complexes and the interference of heteronuclear complex formation on citrate masking reactions. The paper also discusses the existence of heteronuclear cationic hydrolysis products.

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