Abstract

ABSTRACTTwo “core-shell” structured polyorganosilsesquioxanes, differing in the arrangement of vinyl groups over the macromolecule volume, were studied in dilute solutions in toluene and ethyl acetate. It is shown that solution behavior is determined by the transposition of the functional vinyl groups in the core or shell of the macromolecule. This correlation is manifested in increasing the intrinsic viscosity values.

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