Abstract

Surfactant-assisted exfoliated graphene (SAEG) has been implemented in transparent conducting graphene films which, for the first time, were used to make SAEG–silicon Schottky junctions for photovoltaics.

Highlights

  • Chemical doping resulted in a further 300% increase of the peak power conversion efficiency (PCE). These results indicate that surfactant-assisted exfoliated graphene (SAEG) has the potential to compete with chemical vapour deposited graphene in graphene–silicon Schottky junction applications

  • In the last decade nanocarbon–silicon heterojunctions have been investigated for their photovoltaic properties, speci cally carbon nanotube–silicon (CNT–Si)[1] and graphene–silicon (G–Si).[2]

  • Wei et al.[3] were the rst to report a CNT–Si heterojunction in 2007. They used chemical vapour deposition (CVD) to grow a double-walled carbon nanotube lm, a er which the lm was suspended in distilled water and picked up on a prepatterned n-type silicon substrate to create a p(CNT)–n(Si) junction

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Summary

Introduction

In the last decade nanocarbon–silicon heterojunctions have been investigated for their photovoltaic properties, speci cally carbon nanotube–silicon (CNT–Si)[1] and graphene–silicon (G–Si).[2] Wei et al.[3] were the rst to report a CNT–Si heterojunction in 2007. They used chemical vapour deposition (CVD) to grow a double-walled carbon nanotube lm, a er which the lm was suspended in distilled water and picked up on a prepatterned n-type silicon substrate to create a p(CNT)–n(Si) junction. These holes are generated as a result of charge separation at the CNT–Si interface, in which the CNTs are an active layer

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