Abstract
ArF laser photolysis of ferrocene in hexane yields hydrocarbons produced from both intermediate cyclopentadienyl radical and the solvent, and it affords chemical solution-phase deposition of Fe-based particles which consist of a Fe core and oxidized outer layers. These particles are covered with a carbonaceous polymer, they have a characteristic UV spectrum and show both a ferromagnetic ( T = 5 K) and superparamagnetic ( T > 120 K) behaviour.
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