Abstract

AbstractApplying Onsager's theory in one dimension it is shown that there is a finite probability for a carrier to escape geminate recombination with its image charge a t the interface of a molecular crystal and metal even in the absence of an external field. In contrast to the three dimensional case, however, the escape probability is not a strictly linear function of the field and depends on the initial pair separation, even at low fields. Good agreement between theory and experiment is obtained.

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