Abstract
The escape of a Brownian particle across a potential barrier was introduced by Kramers. He derived expressions for the escape or transition rate in the limits of large and small damping. Several expressions that are supposed to be valid for the whole damping regime were put forward some years ago. It seemed that the solution of Matkowsky, Schuss and Tier settled the bridging issue. In this article, however, it will be argued why the mean-first-passage-time approach followed by Matkowsky et al. is not suited to formulate Kramers' problem. An alternative treatment is given based on the Kramers equation which is solved separately in two regions of phase space (corresponding to well and barrier). The escape rate follows from the matching conditions of both solutions. The new expressions resembles the one of Matkowsky et al., but is simpler, and clarifies the connection with unimolecular chemical reactions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Physica A: Statistical Mechanics and its Applications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
