Solute fluxes in headwater catchments with contrasting anthropogenic impact

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Understanding the response of headwater catchments to increasing anthropogenic influences is one of the key issues in hydrological and geomorphological research. Two headwater catchments with contrasting human impacts on the environment were chosen to determine changes in surface water chemistry and solute fluxes. In one catchment, 22 % of the forest area was cleared in 2013 and in the other, 75 % of the arable lands was converted to grassland and forest in the last 25 years. Atmospheric input and solute mass balance were analysed using homogeneity Pettitt test. It seems that in both areas, a very important factor affecting solute fluxes was most likely changes, or lack thereof, in soil erosion. In the partially clear-cut catchment, a small clear-cut area and adequate protection of the soil cover had little effect on the stream water chemistry, and the total solute mass balance remained unchanged during the study period. In this catchment, the more pronounced effect on solute fluxes was using de-icing salts in winter, which contributed to a 62 % increase in total solute flux (mainly by supplying Na+ and Cl−, but also Ca2+, Mg2+ and K+). In a catchment with a decrease in arable lands, there was a 55 % decrease in total solute mass balance (including mass balance of Ca2+, Mg2+, Na+, K+, NH4+, SO4−, NO3−, Cl−) in the stream likely associated with a decrease in soil erosion and fertilization. In both catchments there was a decrease in total monthly atmospheric input (especially in input of NH4+, SO4− and NO3−) of 53 % and 21 %, respectively, over the study period. To summarize, the road salting has increased the amount of transported solutes in the stream and deteriorated surface water chemistry, while the reduction of arable land area has reduced the amount of transported solutes in the stream and improved surface water quality.