‘Solubility parameters’ in coal and coal liquefaction products

Abstract

‘Solubility parameter’ spectra have been used in polymer research to determine the characteristics of cross-linked polymer systems. Cross-linked systems are not soluble in any solvent. Instead, solvent is imbibed by the cross-linked polymer and causes it to swell. The ‘solubility parameter’ of the solvent which causes maximum swelling is identified as that of the cross-linked material. Coal can be thought of as having some characteristics of a cross-linked system 1,2. That is, when immersed in a solvent with which it interacts, it will swell. In addition, coal contains extractable material. If coal is regarded as a ‘multipolymer’, this extractable matter can be thought of as the uncross-linked portion of the coal. Swelling spectra have been taken for untreated coal and coal from which some extractable matter has been removed, which partly suppresses swelling. This extractable matter can be thought of as similar to the uncross-linked coal molecule. Its structure can therefore be used to model the coal matrix itself, to determine the coal structure without using destructive chemical methods to break the coal apart. Dissolution spectra for both the coal extract and the coal liquefaction products from the PAMCO and Synthoil processes were taken. A set of mixed solvents with effective ‘solubility parameters’ ranging from 14.3 to 47.9 MPa 1/2 (7.0 to 23.4 hildebrands) was used. The behaviours of the coal extract and coal liquid products show striking similarities, leading us to believe that molecules similar to those found in liquefaction products already exist in the virgin coal and that hydrogenation products reflect the properties of the starting material.