Abstract
The solubility of triphenyltin chloride (TPT) and triphenylmethyl chloride (TPC) in supercritical carbon dioxide (SC-CO 2 ) was measured with a dynamic method at temperatures from 308.15 K to 338.15 K and pressures ranging from 15 MPa to 40 MPa. The two compounds displayed a similar mole fraction solubility in SC-CO 2 of about 10- 3 to 10 ―4 with a relative uncertainty of about 6 % over the range of experimental conditions. The experimental solubility data were correlated with both empirical Gordillo and semiempirical Chrastil models. The correlation results indicated that the values of average relative deviations (ARD) with the Gordillo model for TPT and TPC were 5 % and 12 %, and those of with the Chrastil model were 9 % and 6 % respectively.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
