Abstract
Solubilities of triethylamine in aqueous calcium chloride solutions were measured at 20, 25, 30, and 35°C. The molalities in CaCl2 of the aqueous solvents ranged from 0.01 to 0.1 mol-kg−1. Data were evaluated from density measurements with a vibrating-tube densimeter. A least-squares method was used to fit experimental density data points, taken at 15°C, to a double polynomial equation. Triethylamine molalities of the saturated aqueous phases were estimated by interpolation from this equation. Solubilities and thermodynamic properties of transfer of Et3N from water to salt solutions were interpreted in terms of hydrophobic and electrostatic perturbed domains in the hydration shells of the nonelectrolyte and of the cation of the salt, as a function of temperature and salt concentration.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
