Abstract
Buchowski, H. and Khiat, A., 1986. Solubility of solids in liquids: one-parameter solubility equation. Fluid Phase Equilibria, 25: 273–278. A new equation for solubility curves has been established based on the variation of vapour pressure over saturated solutions. Melting temperature and entropy of fusion of a pure solid as well as a single constant, depending on both solute and solvent, determine the solubility of the solid in the liquid. The agreement between experimental and calculated solubilities is very satisfactory. The shape of a solubility curve as well as the existence and position of an inflection point are correctly predicted.
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