Abstract
The solid solubility of antimony in cobalt, nickel and Co-Ni alloys has been examined by electron probe microanalysis. It has been ascertained that the solubility of antimony decreases abnormally below the Curie temperature. The compound phase γ-(Co, Ni)Sb equilibrates with the f.c.c. Co-Ni phase at less than 20% Ni, while β-(Ni, Co) 5Sb 2 appears in a region of higher nickel content. These experimental data have been analysed thermodynamically and the phase equilibria in the Co-Ni-Sb system below 50% Sb have been calculated.
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