Abstract

The equilibrium potentials of U3+/U couple, triple U–Ga–In and U–Ga–Al alloys versus Cl−/Cl2 reference electrode in the temperature range 723–823 K in fused LiCl–KCl eutectic in inert atmosphere were carried out by open-circuit potentiometry. The apparent standard potentials of U3+/U couple and triple alloys were determined. The activity, solubility and activity coefficients of uranium in bimetallic liquid Ga–In and Ga–Al eutectic alloys were calculated. The results show the high interaction between uranium and liquid metals due to the formation of intermetallic compounds. The principle thermodynamic properties of triple U–Ga–In and U–Ga–Al alloys were determined.

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