Abstract
Solubilities of the perchlorates of 5-nitro- and 4,7-dimethyl-substituted tris-(1,10-phenanthroline)iron(II) cations in aqueous t-butyl alcohol have been determined. These solubilities are related to effects of the t-butyl alcohol on the structure of the water. They are compared with aquation rates previously reported for these complexes under similar conditions in order to assess the importance of initial-state solvation in determining reactivity. Solubility data for perchlorates of a variety of substituted tris-(1,10-phenanthroline)iron(II) cations in water are also presented and discussed.
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