Solitary Marangoni-driven convective structures in bistable chemical systems

Abstract

Bistable chemical fronts can be deformed by Marangoni-driven convective flows induced by gradients of surface tension across the front. We investigate here the nonlinear dynamics of such a system by simulations of two-dimensional Navier-Stokes equations coupled to a reaction-diffusion-convection equation for a surface-active chemical species present in the bulk of the solution and involved in a bistable kinetics. We show that Marangoni flows cannot only alter the shape and speed of the front but also change the relative stability of the two stable steady states, reversing in some cases the direction of propagation of the front with regard to the pure reaction-diffusion situation. A detailed parametric study discusses the properties of the asymptotic dynamics as a function of the Marangoni number M and of a kinetic parameter d.