Abstract
The solid-to-solid crystallization processes of organic molecules have been poorly understood in view of the complexity and the instability of organic crystals. Here, we studied the crystallization of a π-conjugated small molecular semiconductor, bis-(8-hydroxyquinoline) copper (CuQ2), by annealing the thin films at different temperatures. We observed a classical film-to-nanorods crystallization at 80 °C, a coexistence of classical and nonclassical nucleation and particle growth at 120 °C, and a nonclassical crystal growth at 150 °C. We found that the growth of the crystals followed the following processes: particle nucleation, particle growth, particle migration, nondirectional particle attachment, and structure reconstruction. We notice that the growth of CuQ2 particles follows an outside-to-inside process. More interestingly, our experiments suggest that the submicron CuQ2 particles are able to migrate dozens of micrometers at 150 °C.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.