Abstract

The reaction between silver molybdate and mercuric chlorobromide in solid state was followed by X-ray powder diffraction, chemical analysis, and thermal and electrical conductivity measurements. Kinetics of reaction were studied in detail using a visual technique. Diffusion coefficients of HgClBr were determined. The process is reaction controlled at low temperatures while at high temperatures it is diffusion controlled. Ag 2MoO 4 and HgClBr react in solid state in an equimolar ratio and the reaction proceeds via vapor phase diffusion controlled mechanism.

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