Solidification/stabilization mechanism of Pb(II), Cd(II), Mn(II) and Cr(III) in fly ash based geopolymers

Abstract

Geopolymers are new cementitious materials, which can effectively solidify/stabilize heavy metal ions. Fly ash is an industrial waste from the coal-consumed power plant. With thermal power projects continuously building in the world and the emissions and accumulation quantities of fly ash are increasing yearly. At the same time, with the development of modern industry, waste and waste water containing heavy metals are continuously discharged, so that heavy metal pollution has been the very serious world environmental problems. Aiming at the problem of fly ash and heavy metal pollution, this study referred to solidification/stabilization (S/S) of Pb (II), Cd (II), Mn (II) and Cr (III) in fly ash based geopolymers prepared using composite activator of sodium silicate and sodium hydroxide. The solidification (S/S) results had been explained by means of the leaching and compressive strength of the solidification (S/S) geopolymers (solidified bodies) acquired. The analysis was performed through chemical analysis, X-ray Diffraction (XRD), Fourier Transform Infrared Spectrometer (FTIR), Scanning Electron Microscope (SEM), Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and compressive strength tests. The results indicated that heavy metal ions could be effectively solidified in fly ash based geopolymers with a replacement of safe metal ions like Na (I) and Ca (II). Heavy metal ions had different effects on the compressive strength of geopolymers. (1.5 wt%) Pb (II) was beneficial to improve the compressive strength of geopolymers, and reached 49.34 MPa at 28 d. The XRD patterns indicated an amorphous structure and zeolite-like structure of aluminosilicate. The FTIR patterns study suggested changes of the Si-O-T (T = Si or Al) peak in the geopolymers. The SEM analysis revealed almost condensed homogenous surface of geopolymers. ICP-AES results showed that the geopolymer showed a high degree of solidification (S/S) of the heavy metal ions; in all samples, the solidification rates reached 99.9%. The mechanism of heavy metal ions being solidified was the interaction of physical fixation, adsorption and ion exchange. Finally, the pilot-scale test can achieve the same result on the basis of this study and made preparations for the future of industrialization.