Abstract
In the given work with the purpose of improvement of moistening ability of sulfoborate solid vitreous electrolyte (SVE) in their structure entered molybdenum oxide (VI). Reduction of wetting angle, i.e. improvement of electrode wetting by a SVE-melt, accompanied by better electrode (aluminium) /SVE interface contact formation. Accordingly, the interface impedance is reduced. As a result of the carried out experiments is established, that the modifying SVE by molybdenum oxide (VI) renders complex positive influence on its physical-chemical properties, namely: improves X-ray-amorphism, raises ionic conductivity, reduces electronic conductivity and effective energy of ion conductivity activation. At comparison of properties modified SVE and "LiPON", it is visible, that the ratio between ionic and electronic conductivity for modified SVE approximately on the order is higher, than for "LiPON". Ionic conductivity of the modified SVE higher than conductivity of "LiPON". The low value of electronic conductivity investigated SVE on a background ionic is the positive factor from the point of view of their use in lithium power sources.
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