Abstract
The polycrystalline samples of the x/6Pr6O11 – MoO3 (2 ≤ x ≤ 6) series were prepared by conventional solid-state route. The phase formation was studied by XRD analysis in the temperature range of 1000 – 1200 °C. After calcination at 1100 °С, the formation of praseodymium molybdate with Pr4MoO9+δ composition is observed, which decomposes into a mixture of Pr2MoO6 and Pr6MoO12+δ phases at 1200 °С. It was first established that Pr4MoO9+δ praseodymium molybdate has a monoclinic lattice with parameters a = 16.7211(9) Å, b = 11.9894(7) Å, c = 9.5588(5) Å, β = 109.6149(7) °, sp. gr. C 2/m. Crystal structure was refined by high resolution neutron diffraction data. The homogeneity regions of Pr4MoO9+δ and Pr6MoO12+δ were determined to be 4 < x < 4.2 and 4.57 < x < 6, respectively. It was shown that the conductivity of this molybdates increases with praseodymium oxide content in the Pr5Mo3O16+δ – Pr4MoO9+δ – Pr6MoO12+δ series.
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