Abstract
Solid-state structural transformation of two polymorphic forms of [Ag(8-HqH)(8-Hq)]n (1α and 1β, where 8-HqH = 8-hydroxyquinoline and 8-Hq(-) = 8-hydroxyquinolate) to {[Ag(8-HqH)2]NO3}n (2) has been observed upon solid-gas reaction of compounds 1α and 1β with HNO3 vapors. Solid-gas reaction of compound 2 with hydrated vapors of NH3 results in the formation of only the 1β polymorph, while solid-solid reaction of compound 2 with KOH results in the formation of a 1α and 1β mixture with chiral and achiral space groups of P2(1)2(1)2(1) and Pbcn, respectively.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
