Abstract
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal-organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
Highlights
A number of highly crystalline organic polymers can be made in the solid state from a variety of monomers.1 In contrast, organic polymers containing pendant metal complexes are known,2 their solid state structures could not be determined due to their very low crystallinity
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal–organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer
We have observed that such a metal complex of an organic polymer ligand can be obtained indirectly by the [2+2] cycloaddition reaction in the solid state
Summary
A number of highly crystalline organic polymers can be made in the solid state from a variety of monomers.1 In contrast, organic polymers containing pendant metal complexes are known,2 their solid state structures could not be determined due to their very low crystallinity. The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal–organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
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