Abstract
Reactions of imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz) and 1,3-diazipane-2-thione (Diap) with mercury(II) selenocyanate in acetonitrile resulted in formation of 2 : 1 complexes. Both solid state and solution NMR, confirm the exocyclic sulfur atom to be the donor in all cases. 199Hg shielding tensors and anisotropies were calculated from the solid-state NMR spectra. Based on the solid NMR data a distorted tetrahedral disposition of ligands around mercury is proposed.
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