Solid–solid interactions in Co 3O 4–MoO 3/MgO system

Abstract

Cobalt/magnesium mixed oxide solids and cobalt–molybdenum/magnesium mixed oxide solids were prepared by thermal decomposition of basic magnesium carbonate pretreated with different proportions of cobalt nitrate and then with calculated amounts of ammonium molybdate. The proportions of cobalt expressed as Co 3O 4 were 0.1, 0.2 and 0.3 mol while the concentrations of molybdenum expressed as mol% MoO 3 were 2.5 and 5.0. The prepared mixed solid specimens were calcined in air at 400–1000 °C. The solid–solid interactions in Co 3O 4–MoO 3 were investigated using DTA, TG and X-ray powder diffraction (XRD) techniques. The results obtained revealed that MgO dissolved cobalt oxide in its lattice forming CoO–MgO solid solution. The amount of cobalt dissolved increases by increasing the temperature in the range 800–1000 °C. This finding was confirmed by X-ray diffractograms in which all the diffraction lines of cobalt oxide disappeared at 1000 °C. MoO 3 present interacted readily with MgO and cobalt oxide by heat treatment at temperature starting from 400 °C producing MgMoO 4 and CoMoO 4 which remained stable by heating at 1000 °C. The impregnation of basic magnesium carbonate with cobalt nitrate much enhanced its thermal decomposition yielding MgO, which decomposed completely at 395.5 °C instead of 525 °C. The formation of magnesium cobaltite (MgCo 2O 4) has been ruled out via XRD investigation at relatively high diffraction angles.