Abstract

Thermal methods were used to determine with high precision the solid-liquid phase equilibria diagram for water + ethylene glycol. A stable 1−1 solid hydrate forms. Because of supercooling, the hydrate is difficult to obtain; a cooling procedure was devised to initiate its crystallization. The two eutectics are at (224.12 ± 0.05) and (230.22 ± 0.05) K and mole fractions 0.288 and 0.541 of ethylene glycol, respectively. We also obtained a metastable phase diagram with a single metastable eutectic at (209.5 ± 0.5) K and mole fraction 0.335 of ethylene glycol.

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