Sol-gel Synthesis and Upconversion Luminescent Properties of Yb3+,Er3+,Eu3+ Triply-Doped in YVO4 Phosphors.

Abstract

Yb3+,Er3+,Eu3+ triply-doped in YVO4 with varying molar ratio of Er/Eu were synthesized in a sol-gel method with a subsequent heat treatment for the first time. The optimal molar ratio of Er/Eu for the maximum energy transfer efficiency was 1/39. After molar ratio, the influences of different heat treatment temperatures were also researched and the maximal heat temperature was 1300°C. Besides, the properties of YVO4:Yb3+,Er3+,Eu3+ upconversion phosphors were investigated by X-ray diffraction, scanning electron microscopy and photo luminescent spectra, respectively. In sum, XRD results indicate the crystal structure of as-prepared samples, which is the tetragonal phase of YVO4 with no other diffraction peaks. SEM images show the morphology of as-prepared samples, which are granular-like nanoparticles. PL spectra demonstrate the upconversion luminescence of as-prepared samples, which emit strong green lights (at 525nm, 550nm) and slight red lights (at 590nm, 615nm, 695nm) under the NIR irradiation at 980nm. Two strong green emissions are attributed to the 2H11/2→4I15/2 and 4S3/2→4I15/2 transitions of Er3+ ions. Meanwhile, three slight red emissions are attributed to the 5D0→7F1, 5D0→7F2 and 5D0→7F4 transitions of Eu3+ ions. All in all, the colorful emissions endow YVO4:Yb3+,Er3+,Eu3+ phosphors great potential for some applications, such as display devices, bio-labeling and infrared detection.