Abstract

The bentonite pellet-contained material (PCM) is a desired joint sealer for high-level radioactive waste repositories. During the operation of the repository, however, the PCM is unsaturated for most of the period. The water retention capacity and permeability of PCM can thus directly affect the bentonite buffer barrier seepage, nuclide migration, and joint healing. Moreover, the performance of PCM can be strongly influenced by the particle size of bentonite pellets and dry density. In this work, the pressure plate method and vapor equilibrium technique were both utilized to test the soil–water characteristic curves (SWCCs) of the PCMs with varying particle sizes and dry densities. The unsaturated hydraulic conductivity of the PCMs was then predicted by combining the SWCC model and saturated hydraulic conductivity. The results showed that in the low suction range (20–1150 kPa), the dry density and particle size are anti-correlated with the water content. In the high suction range (4200–309,000 kPa), the SWCC is almost insensitive to the variation of dry density and particle size. The Gardner model is suitable for describing the SWCC of PCM. In addition, the hydraulic conductivity of the PCM increases with the rise in particle size, while it decreases as the dry density grows. Finally, the influence mechanism of the SWCC and hydraulic conductivity was further discussed based on the scanning electron microscopy images and pore size distribution curves.

Highlights

  • Nuclear energy, with its advantages of cleanliness, safety, and stability, is one of the essential ways to solve the current energy crisis (Peng et al 2021)

  • In the low suction range (20–1150 kPa), the dry density had a great influence on the soil-water characteristic curves (SWCCs)

  • The SWCCs of pellet-contained material (PCM) with different particle sizes were different in the low suction range, indicating that the bentonite pellets became homogeneous with the bentonite powder on the macro-level after saturation, the interior of the PCM was still inhomogeneous on the micro-level

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Summary

Introduction

With its advantages of cleanliness, safety, and stability, is one of the essential ways to solve the current energy crisis (Peng et al 2021). Further related research needs to be carried out This can provide a basis for sample preparation in the study of water retention and permeability of the GMZ PCM. The particle size of bentonite pellets and dry density are important factors affecting the performance of the GMZ PCM. Discussing the influence of particle size and dry density on the SWCC and hydraulic conductivity of GMZ PCM is of great significance to the theoretical analysis and engineering application of joint sealing materials (Lee et al 1999; Zhang et al 2016). Based on the microstructure, the influence mechanism of dry density and particle size on the SWCC and hydraulic conductivity of PCM was discussed. The results can provide a theoretical basis for screening joint sealing materials and optimizing the joint design of buffer barriers for HLW disposal

Test materials
Preparation of bentonite pellets
Optimum pellet percentage of PCM
Packing density
Free swelling ratio
Sample preparations
Test methods
Microstructure tests
Relationship between dry density and SWCC
Relationship between particle size of bentonite pellets and SWCC
Selection of SWCC model
Prediction of unsaturated hydraulic conductivity
Influence mechanism of SWCC and hydraulic conductivity
Conclusions
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