Soil–air partitioning of volatile organic compounds into soils with high water content

Abstract

Environmental contextAssessing environmental and human health impacts of chemical spills relies on information about how chemicals move across multiple environments. We measured volatile contaminants in the air above soil saturated with water to provide estimates of air concentrations of selected chemicals released to soil from an oil refinery in Texas during Hurricane Harvey. Estimated concentrations were below recommended exposure limits, even in a worst-case scenario. AbstractThe emission of volatile organic compounds (VOCs) from soil into air is affected by soil moisture dynamics, soil temperature, solar irradiance and carbon availability. The high amount of water in soil can modify its properties, which changes how VOCs interact. We conducted a comprehensive measurement of the soil–air partition coefficient (KSA) of VOCs into water-saturated soil with both low and high water contents for polar, weakly polar and nonpolar VOCs into a mineral soil (S-clay) and soil containing a high amount of organic matter (S-om) under a water-saturated condition. Partitioning of non-polar substituted aromatics (1,2-dichlorobenzene and toluene) was sensitive to the organic matter content in water-saturated soil. 1,2-Dichlorobenzene and toluene had higher affinities to S-om than to S-clay at all investigated water contents because of their strong interaction with the organic matter in soil. KSA decreased with elevated water content only for non-polar substituted aromatic VOCs. Less hydrophobic VOCs (benzene and trichloroethylene) exhibited similar partitioning into both soils by sorbing onto the air-water interface and dissolving in soil water, while the organic matter did not affect partitioning. The weakly polar and polar VOCs (methyl tert-butyl ether and 1-butanol) showed similar partitioning into both soils by dissolving in soil water while sorption to the organic matter was significant only at high soil water contents. KSA of VOCs on soil with high organic matter content correlated strongly with psat and Koa, but not on mineral soil. Estimates of the air concentrations for a subset of VOCs released from one refinery during Hurricane Harvey in 2017 in Harris County, Texas were lower than the recommended exposure limits, even under a worst-case scenario.