Abstract

ABSTRACT Steel slag presents potential for neutralizing the soil acidity instead of limestone and for supplying nutrients for plants. The objective of this work was to study the effect of steel slag on soil chemical characteristics, biomass production, and contents of nutrients and of heavy metals on dry matter of corn plants. The levels of P, K, Na, Ca, Mg, Cu, Fe, Zn, Mn, Si, Cd, Cr, Pb, and Ni were determined in steel slag and limestone (for comparison purposes) and the growth of corn plants under increasing doses of slag and limestone (0 to 10 t ha-1) was evaluated. Steel slag presented higher levels of P, Fe, Zn, Mn, and Si when compared with limestone. No difference was found in the content of heavy metals of slag and limestone, except for Cr, which was higher in the slag. Limestone provided the greatest increase of soil pH over time. Slag increased the content of P, Si, and soil micronutrient, while limestone was more efficient in increasing the content of Mg. The levels of heavy metals in the soil increased with the application of slag, but they remained below critical level within agricultural parameters. Slag and limestone presented a similar effect on the increase of the initial production of corn biomass. The levels of heavy metals in dry matter of corn plants under increasing doses of slag and limestone were below the critical levels of the toxicity of these elements on most plants.

Highlights

  • Slags are products resulting from industrial processes aimed at obtaining pig iron first, and for steel

  • The objective of this work was to study the effect of steel slag compared to limestone on soil chemical characteristics, biomass production and contents of nutrient and heavy metals in the dry matter of corn plants

  • Samples from LD steel slag from the Arcelor Mittal Tubarão Steel Industry, located in the municipality of Serra, state of Espírito Santo, (20° 14' 16,6" S; 40° 13' 59,5"W), were sieved in 2-mm mesh and after that, their contents of P, K, Na, Mg, Cu, Fe, Zn, Mn and Si were determined according to the methodology described by the Ministério da Agricultura, Pecuária e Abastecimento (1988) and the contents of Cd, Cr, Pb and Ni were set by the method according to Embrapa (1997)

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Summary

Introduction

Slags are products resulting from industrial processes aimed at obtaining pig iron first, and for steel. Steel slag is generated in the steelmaking process, resulting from the transformation of liquid pig iron into steel. Brazil is the sixth leading producer of pig iron in the world, with an annual production of about 25 million tons. The state of Minas Gerais is the largest producer, accounting for more than a half of all pig iron and steel domestically produced. The Brazilian steel industry currently generates approximately six million tons of steel slag per year (Ramos et al, 2016). In the state of Espírito Santo, Arcelor Mittal Tubarão produces about 86.2 kg of this slag per ton of liquid steel, resulting in approximately 415 thousand tons of slag per year (Arcelor Mittal Tubarão, 2016)

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