Abstract
The X-ray absorption near-edge structure (XANES) spectra of C 76 and fluorinated C 60 (C 60F x ) were measured. By comparing XANES and inverse photoemission spectra for various π-electron systems, the deviation of XANES from density of unoccupied states (DOUS) by core-excitonic effect was shown to decrease with increasing size and dimensionality. The deviation is not so large for fullerenes, and the spectrum of C 76 was compared with calculated DOUS. The change of bonding and electronic structure from C 60 to C 60F x is also discussed based on the XANES spectra.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
