Abstract

ε-Fe3N can be flexibly synthesized via a sol-gel route by using ethylenediamine as the nitrogen source, and the role of ethylenediamine can be demonstrated by adjusting the molar ratio of ethanediamine to acetone. Excellent magnetic properties (72.35 emu/g) and coercivity are obtained at the optimized condition, showing the potential applications in magnetic material field. In addition, the probable formation mechanism of iron nitride is investigated in this article, supported by XRD patterns and etc, which has important effect on the further research of the iron nitride via a sol-gel route.

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