Abstract

Biomass materials are promising precursors for the production of carbonaceous materials due to their abundance, low cost and renewability. Here, a freestanding wrinkled carbon membrane (WCM) electrode material for flexible supercapacitors (SCs) was obtained from flower petal. The carbon membrane was fabricated by a simple thermal pyrolysis process and further activated by heating the sample in air. As a binder and current collector-free electrode, the activated wrinkled carbon membrane (AWCM) exhibited a high specific capacitance of 332.7 F/g and excellent cycling performance with 92.3% capacitance retention over 10000 cycles. Moreover, a flexible all-solid supercapacitor with AWCM electrode was fabricated and showed a maximum specific capacitance of 154 F/g and great bending stability. The development of this flower petal based carbon membrane provides a promising cost-effective and environmental benign electrode material for flexible energy storage.

Highlights

  • Biomass materials are promising precursors for the production of carbonaceous materials due to their abundance, low cost and renewability

  • The synthesis of these nanocarbons suffers from the drawbacks of the high cost chemical vapor deposition (CVD) process or the environmental issues related to the usage of toxic chemicals

  • wrinkled carbon membrane (WCM) was prepared by a thermal pyrolysis process at 1000 °C under the protection of Ar

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Summary

Introduction

Biomass materials are promising precursors for the production of carbonaceous materials due to their abundance, low cost and renewability. A freestanding wrinkled carbon membrane (WCM) electrode material for flexible supercapacitors (SCs) was obtained from flower petal. As a binder and current collector-free electrode, the activated wrinkled carbon membrane (AWCM) exhibited a high specific capacitance of 332.7 F/g and excellent cycling performance with 92.3% capacitance retention over 10000 cycles. A flexible all-solid supercapacitor with AWCM electrode was fabricated and showed a maximum specific capacitance of 154 F/g and great bending stability The development of this flower petal based carbon membrane provides a promising costeffective and environmental benign electrode material for flexible energy storage. The carbon membrane is highly flexible and a symmetric all-solid SC with high flexibility was fabricated, which exihibits a specific capacity of 154 F/g, outperforming other porous carbon based SCs. The performance of the device under bending is very stable and no apparent capacitance decay was found after 10 bending cycles

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