Abstract
In the title compound, Na+·C6H4BrClNO2S−·1.5H2O, one water molecule has crystallographically imposed twofold symmetry. The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-bromo-2-chlorobenzenesulfonamidate anions. The S—N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O—H⋯Br, O—H⋯N and O—H⋯O hydrogen bonds.
Highlights
In the title compound, Na+C6H4BrClNO2S1.5H2O, one water molecule has crystallographically imposed twofold symmetry
H atoms treated by a mixture of independent and constrained refinement max = 2.27 e Å3
The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-bromo-2-chlorobenzenesulfonamidate anions
Summary
B. Thimme Gowda,a* Sabine Forob and K. Shakuntalaa a Department of Chemistry, Mangalore University, Mangalagangotri 574 199, Mangalore, India, and bInstitute of Materials Science, Darmstadt University of Technology, Petersenstrasse 23, D-64287 Darmstadt, Germany. R factor = 0.049; wR factor = 0.128; data-to-parameter ratio = 15.2
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