Abstract
The structure of NaMg(H2PO3)3·H2O belongs to the isotypic dihydrogenphosphite monohydrate series NaM(H2PO3)3·H2O (M = Mn, Co and Zn), with alternating NaO6 [dav(Na—O) = 2.466 (2) A] and MgO6 [dav(Mg—O) = 2.086 (2) A] octahedra, crosslinked by H2PO3 pseudo-pyramids [dav(P—OMg) = 1.530 (2) A and dav(P—OH) = 1.575 (2) A].
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