Abstract
Sodium hydrogen trans-glutaconate (sodium hydrogen trans-pent-2-ene-1,5-dioate, Na + .C 5 H 5 O 4 - ), (I), crystallizes in the monoclinic space group P2 1 /n with Z = 4, and ammonium hydrogen trans-glutaconate (ammonium hydrogen trans-pent-2-ene-1,5-dioate, NH 4 + .C 5 H 5 O 4 - ), (II), crystallizes in the orthorhombic space group Ibam with Z = 8. In both crystals, a non-centrosymmetric O-H...O hydrogen bond is formed between the carboxyl and carboxylate groups of neighboring anions. The Na + cation in (I) is coordinated by six O atoms. There are two symmetry-independent NH 4 + cations in (II). The number of hydrogen bonds around each NH 4 + cation is four.
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