Sodium dodecyl sulfate improves the properties of bio-based wood adhesive derived from micronized starch: Microstructure and rheological behaviors

Abstract

Enhancing the performance of starch-based wood adhesive is vitally important for its practical applications. Accordingly, we designed the use of micronized starch (MS) to prepare micronized starch-based wood adhesive (MSWA) by incorporating 0, 2, 4 and 6% (w/w, dry basis starch) sodium dodecyl sulfate (SDS). The results showed that 2% SDS exhibited remarkable improvement in shear strength and viscosity of MSWA. The grafted reaction was demonstrated by 1H NMR and the steady shear results indicated that the adhesive possessed a pseudoplastic behavior under yield stress conditions. Besides, dynamic rheological measurements were applied to evaluate the structure of MSWA under varying frequencies, temperatures and constant stain. The transmission electron microscopy (TEM), Zeta potential and surface tension indicated that SDS could improve the surficial properties. Meanwhile, the microstructure of adhesive films and fracture surfaces of glued wood veneers by scanning electron microscopy (SEM) demonstrated that the migration of SDS led to the formation of surfactant layer. Furthermore, element analysis revealed the distribution of S/N in latex slices. The results of this study provide the detailed information about the influence of SDS on the rheological properties and microstructures of MSWA, which may facilitate the preparation of high performance bio-based adhesive for wood applications.