Sodium citrate-sodium hydroxide synergy on remediating asphaltene-contaminated solids

Abstract

Asphaltenes are the heaviest and surface-active polyaromatic compounds in crude oil. Their precipitation and deposition on sand surfaces switch the wettability of sand from water-wet to oil-wet, which is harmful to the oil recovery process. In this study, we demonstrate the synergistic effect between sodium hydroxide (NaOH) and sodium citrate (Na3Cit) on remediating asphaltene-contaminated silica from both experimental and molecular dynamics (MD) simulation perspectives. Asphaltene desorption efficiency increased from 39 % (Na3Cit only) to 84 % (NaOH + Na3Cit), attributed to better remediation of natural silica wettability and reduced silica-asphaltene adhesion with the co-addition chemicals. Fundamental insights for NaOH-Na3Cit synergy were revealed by MD simulation. The bonding between an asphaltene model compound (C5Pe) and the quartz (101) surface became thermodynamically less favorable when both NaOH and Na3Cit were present in the system, forcing the C5Pe molecules to move away from the surface. In summary, we highlight the NaOH-Na3Cit synergy in promoting the asphaltene detachment from silica surfaces, which has important implications in oil recovery and soil remediation applications.