Abstract
Selective reduction of a wide range of aromatic and aliphatic aldehydes to the corresponding alcohols with NaBH4 was achieved in the presence of an oxovanadium(IV) Schiff base complex encapsulated in the nanopores of zeolite Y (VOL-Y). For most of the aldehydes, a conversion of 100% was observed after less than 5min. High chemoselectivity of the reduction for aldehydes over ketones was verified by a competitive reduction between 4-methylbenzaldehyde and acetophenone.
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